28 فروردین 1403

پریسا دارائی

مرتبه علمی: استادیار
نشانی: دانشکده انرژی، گروه مهندسی شیمی
تحصیلات: دکترای تخصصی / شیمی کاربردی
تلفن:
دانشکده: دانشکده مهندسی

مشخصات پژوهش

عنوان
Nanoclay embedded mixed matrix PVDF nanocomposite membrane : preparation, characterization and biofouling
نوع پژوهش مقاله چاپ شده
کلیدواژه‌ها
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پژوهشگران حمید رجبی (نفر اول)، نگین قائمی (نفر دوم)، سعید مدائنی (نفر سوم)، پریسا دارائی (نفر چهارم)، محمد علی خدیوی (نفر پنجم)، منیر فلسفی (نفر ششم به بعد)

چکیده

In this paper, nanocomposite PVDF/nanoclay membranes were prepared with addition of different concentrations of organically modified montmorillonite (OMMT) into the polymeric casting solution using combination of solution dispersion and phase inversion methods. Membranes were characterized by use of X-ray diffraction (XRD), water contact angle, scanning electron microscopy (SEM) and atomic force microscopy (AFM), and their performances were evaluated in terms of pure water flux and fouling parameters. The surface hydrophilicity of all nanocomposites markedly improved compared to nascent PVDF. In addition, XRD patterns revealed the formation of intercalated layers of mineral clays in PVDF matrix. SEM and AFM images showed that addition of OMMT resulted in nanocomposite membranes with thinner skin layer and higher porosity rather than PVDF membranes. Pure water flux of PVDF/OMMT membranes increased significantly (particularly for fabricated membranes by 4 and 6 wt.% OMMT) compared to that of PVDF membrane. Moreover, nanocomposite membranes showed the elevated antifouling properties, and flux recovery of nascent PVDF membranes increased from 51 to 72% with addition of 2 wt.% OMMT nanoparticles. These nanocomposite membranes also offered a remarkable reusability and durability against biofouling.