Passive latent heat thermal energy storage approach incorporating phase change materials (PCM) is a brilliant
technique to tackle high energy consumption issue in buildings. This paper investigated the thermal performance
of the conventional walls of buildings in Isfahan, Iran with the inclusion of thirteen different phase change
materials. The studied base wall was composed of plaster (2 cm), clay brick (15 cm), and cement (3 cm). The
effect of PCM position inside the wall on the heat transfer was assessed in two scenarios, namely: close to the
interior and close to exterior. The nonlinear governing equations were solved using the finite volume method.
The results show that the performance of PCM-based wall is strongly influenced by the thermal conductivity,
phase-change enthalpy and melting temperature of PCM. A PCM can more efficiently reduce the heat transfer to
the interior space in case it has a lower thermal conductivity, has a higher latent heat of phase-change, and its
phase-change temperature is closer to the room temperature. Moreover, the thermal conductivity has priority
over other PCM thermophysical properties. The lower PCM thermal conductivity leads to transfer the lower
amount of heat to the interior space. A two-fold increase in the thickness of the PCM leads to less than a twofold
reduction in the heat transfer. Among the studied PCMs, the heat transfer reduction by Enerciel 22 was within
the range 15.6–47.6%, while this range was 2–7.8% for CaCl2. 6H2O.